Round 1
- 15 Aug 2025, 18:00 (GMT/UTC)GironavsRayo Vallecano
- 15 Aug 2025, 20:30 (GMT/UTC)VillarrealvsReal Oviedo
- 16 Aug 2025, 18:30 (GMT/UTC)MallorcavsBarcelona
- 16 Aug 2025, 20:30 (GMT/UTC)ValenciavsReal Sociedad
- 16 Aug 2025, 20:30 (GMT/UTC)Deportivo AlavesvsLevante
- 17 Aug 2025, 16:00 (GMT/UTC)Celta de VigovsGetafe
- 17 Aug 2025, 18:30 (GMT/UTC)Athletic BilbaovsSevilla
- 17 Aug 2025, 20:30 (GMT/UTC)EspanyolvsAtlético de Madrid
- 18 Aug 2025, 20:00 (GMT/UTC)ElchevsBétis
- 19 Aug 2025, 20:00 (GMT/UTC)Real MadridvsOsasuna
